By:Tong, Xiaogang;Shi, Bingfei;Liu, Qian;Huo, Yanman;Xia, Chengfeng
Organic & biomolecular chemistry
Published:2019-Aug-21(Epub 2019 Aug 21)
Document Type:Journal Article
Rhynchophylline alkaloids are bio-synthesized from corynanthe alkaloids via an oxidative rearrangement. We demonstrate here that corynanthe alkaloids could be generated from rhynchophylline alkaloids in a retro-biosynthetic manner via a Wagner-Meerwein rearrangement. A series of corynanthe analogues were afforded with good functional group tolerance and satisfactory yields.
Addresses:Key Laboratory of Medicinal Chemistry for Natural Resource(Ministry of Education and Yunnan Province), School of Chemical Science and Technology,Yunnan University, Kunming 650091, China. email@example.com.
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